In a title-winning season for Barcelona, the two players with the highest average rating are from this Barcelona squad: Frenkie de Jong and Pedri.
| Player | Rating | Defense | Minutes Played | Team |
| Frenkie de Jong | 7.95 | Back 4 | 2450 | Barcelona |
| Pedri | 7.79 | Back 4 | 1886 | Barcelona |
| Sergi Darder | 7.76 | Back 5 | 779 | Espanyol |
| Toni Kroos | 7.62 | Back 4 | 2149 | Real Madrid |
| Aleix García | 7.58 | Back 5 | 706 | Girona |
| Vinicius Júnior | 7.55 | Back 4 | 2823 | Real Madrid |
| Daniel Parejo | 7.54 | Back 4 | 3285 | Villarreal |
| Federico Valverde | 7.47 | Back 4 | 2497 | Real Madrid |
| Lee Kangin | 7.47 | Back 5 | 681 | Mallorca |
| Rodrygo | 7.46 | Back 4 | 1295 | Real Madrid |
| Sergio Busquets | 7.44 | Back 4 | 2332 | Barcelona |
| Dani Ceballos | 7.37 | Back 4 | 1542 | Real Madrid |
| A. Tchouaméni | 7.20 | Back 4 | 2107 | Real Madrid |
| Oriol Romeu | 7.17 | Back 5 | 630 | Girona |
| Mikel Merino | 7.15 | Back 4 | 2494 | Real Sociedad |
| Raphinha | 7.11 | Back 4 | 2028 | Barcelona |
| Koke | 7.11 | Back 5 | 1752 | Atlético Madrid |
| Marcos Llorente | 7.11 | Back 5 | 611 | Atlético Madrid |
| Sergi Darder | 7.08 | Back 4 | 2181 | Espanyol |
| André Almeida | 7.06 | Back 4 | 2255 | Valencia |
| Isi Palazón | 7.05 | Back 4 | 2875 | Rayo Vallecano |
| Joan Jordán | 7.04 | Back 5 | 594 | Sevilla |
| Viktor Tsyhankov | 7.02 | Back 4 | 1310 | Girona |
| Javier Guerra | 7.01 | Back 4 | 527 | Valencia |
| Rodrigo De Paul | 7.00 | Back 5 | 1277 | Atlético Madrid |
Conditions for the presented data:
– Minimum minutes played in the season: 450 minutes (equivalent to 5 full games) per type of defense played (Back 4 or Back 5);
Data from FBref.